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Electro-oxidation of Br −  on platinum and gold electrode was studied in acetonitrile, methanol and mix media of acetonitrile–methanol. The mechanism of Br −  oxidation in these media was investigated using CV, Semi Integration Cyclic Voltammetry, and Digital Simulation technique. Since, Br −  oxidation mechanism on platinum involves the formation of Br 3  −  as intermediate, therefore, K stab  for Br 3  −  formation in the mixed media was estimated using digital simulation, Nelson and Iwamoto method. Redox mechanism of Br −  and Br 2  on gold (Au) electrode was also investigated in protic solvent such as H 2 O, methanol, ethanol, 1-butanol, and formic acid. It was ascertained that Br −  oxidation on gold (Au) electrode in these above protic solvents involve [AuBr 2 ] −  intermediate rather than Br 3  − .

zeitschrift für physikalische chemie

Electrochemistry of Br − /Br 2  Redox Couple in Acetonitrile, Methanol and Mix Media of Acetonitrile–Methanol: An Insight into Redox Behavior of Bromide on Platinum (Pt) and Gold (Au) Electrode