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From the cultures of spore-derived mycobionts of the lichen Lecanora leprosa a novel naphtho[1,8-cd]pyran-3-one derivative, lecanopyrone, was isolated. Its structure was determined by spectroscopic methods. The assembly pattern of acetate units in its biosynthesis was verified using sodium [1- 13 C]-acetate and sodium [1,2- 13 C 2 ]-acetate

Structure and Biosynthesis of Lecanopyrone, a Naphtho[1,8-cd]pyran-3-one Derivative from Cultured Lichen Mycobionts of Lecanora leprosa