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The series of complexes: cis-[Pd(PMSA) 2 X 2 ], cis-[Pt(PMSA) 2 X 2 ], trans-[Pt(PMSA) 2 I 2 ] and [Pt(PMSA) 4 ]Cl 2  (PMSA = N-3-pyridinylmethanesulfonamide; X = Cl, Br, I), previously synthesized and characterized by us, as well as the free ligand PMSA, were tested for their cytotoxic activity without electroporation - against murine leukemia F4N and human SKW-3 and MDA-MB-231 tumour cell lines - and with electroporation - against the latter two cell lines. The majority of the complexes exhibited cytotoxic effects (IC 50  &lt; 100 μmol/l) under the conditions of electroporation. Both cis- and trans-[Pt(PMSA) 2 I 2 ] had pronounced cytotoxic effects (29 - 61 μmol/l against MDA-MB-231 cells).

Cytotoxic Activity of Platinum(II) and Palladium(II) Complexes of N-3-Pyridinylmethanesulfonamide: the Influence of Electroporation