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A new valerenane sesquiterpenoid, methyl valerenate (1), was found in the essential oil from underground parts of Valeriana officinalis L. s.l. Spectral data of methyl valerenate, which was synthesized from valerenic acid (2), are given in this paper.

Methyl Valerenate, a New Sesquiterpenoid in the Essential Oil from Underground Parts of Valeriana officinalis L. s.l.