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A phytoalexin produced by the leaflets of seven cultivars of Arachis hypogaea (groundnut) after natural infection by Cercospora arachidicola or Phoma arachidicola has been characterised as the isoflavonoid (+)-medicarpin (3-hydroxy-9-methoxypterocarpan). Treatment of excised ground­nut leaflets with an aqueous solution of CuSO 4  or with a spore suspension of the fungus Helmin-thosporium carbonum has also been found to stimulate medicarpin biosynthesis.

Isolation of the Phytoalexin Medicarpin from Leaflets of Arachis hypogaea and Related Species of the Tribe Aeschynomeneae