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The X-ray Structure of Silybin from Silybum marianum Gaertn. was determined. The com­pound was found to be a diastereomeric mixture (1:1) in the benzodioxane part of the molecule explaining several tentative aspects about the structure known from NMR-measurements and HPLC-separations.

Zur Stereochemie von Silybin / The Stereochemistry of Silybin