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Acetalation of the cis-diol moiety of adenosine or inosine with aliphatic ketoesters of different chain lengths leads to alkylidene derivatives of the nucleosides, which differ in the number of methylene groups in the hydrocarbon chain. By alkaline hydrolysis of the ester group in 1a - c or 3a - c the corresponding acids 2a - c and 4a - c have been prepared.

zeitschrift für naturforschung c

Immobilisierung von Adenosinacetalen mit variablem Alkylidenrest — die Funktion des Spacers bei enzymatischer Desaminierung / Immobilization of Adenosine-Acetals with Variable Alkylidene Residues — the Function of the Spacer during Enzymatic Deamination —