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[ω- (3-Acetylpyridinio) -n-alkyl] adenosine pyrophosphates are coenzyme analogs of NAD ⊕ . The adenosine pyrophosphate moiety and the 3-acetylpyridine ring of the analogs are connected by n-alkyl chains of different lengths (ethyl -hexyl). The analogs form strong dissociating complexes with lactate dehydrogenase. The complex formation is predominantly achieved by interaction of the ADP moiety with its respective binding domain at the active site.

zeitschrift für naturforschung c

Eigenschaften der [ω-(3-Acetylpyridinium)-n-alkyl]-adenosin-pyrophosphate als Strukturanaloge des Coenzyms NAD / The Properties of [ω-(3-Acetylpyridinio)-n-alkyl] Adenosine Pyrophosphates, Structural Analogs of the Coenzyme NAD