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Erythritol-1-d 1  has been isolated from γ-irradiated aqueous oxygenated solution of DNA after reduction with NaBD 4  , alkali and phosphatase treatment. It is concluded that this product stems from a ᴅ-erythrose 2,4-diphosphate unit in the DNA which is formed via a sequence of reactions following H-abstraction at C-2′ by OH radicals..

γ-Radiolyses of DNA in Oxygenated Aqueous Solution. Structure of an Alkali-Labile Site