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The dimetallacyclic complex H 2 C(Me 2 SiC≡CAuPMe 2 ) 2 CH 2  has been synthesized, in which the two gold centers are bridged by the diphosphine dmpme (= bis(dimethylphosphino)methane) and a diethynyl ligand providing “full support” for the possible transannular Au–Au contact ( 3 ). This compound and its “semi-” and “unsupported” analogues ( 2 ,  1 ) have been characterized by NMR spectroscopy and elemental analysis. The monomeric nature of complex  3  in solution has been established using diffusion coefficients measured by DOSY-NMR spectroscopy and comparing the data with those of complexes  1  and  2  as references.

Constitution of the fully supported gold(I)alkynyl (dmpme)·bis[gold(I)ethynyldimethylsilyl]methane in solution