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A metal-organic framework (MOF) {[Cd(EtOIPA)(bpp)(H 2 O)]·2H 2 O}   n    ( 1 ) has been synthesized under basic hydrothermal conditions by using of 5-ethoxyisophthalic acid (EtOIPAH 2 ) and 1,3-bis(4-pyridyl)propane (bpp) as reagents for cadmium nitrate. Compound  1  was characterized by elemental analysis, single-crystal X-ray diffraction and UV/Vis spectroscopy. In  1 , the bpp ligands extend the EtOIPA-Cd chains along the  ab  plane to form a 2-fold 3D interpenetrating network. Compound  1  emits blue phosphorescence at room temperature with a long lifetime of 4.2 ms.

zeitschrift für naturforschung b

A Cd(II) MOF based on 5-ethoxyisophthalate and 1,3-bis(4-pyridyl)propane ligands with a twofold interpenetrated crystal structure showing room temperature phosphorescence