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The isothermal section of the Sc–Co–In system at  T  = 870 K has been constructed using X-ray powder diffraction and SEM/EDX data. At the studied temperature, nine ternary compounds are formed: Sc 50 Co 12.5 In 3.5  (Ag 7+ x   Mg 24− x   -type structure, space group  Fm3   ‾$\overline{3}$,  a  = 17.7411 Å), Sc 14 Co 3.10 In 2.59  (Lu 14 Co 3 In 3  type,  P 4 2 / nmc ,  a  = 8.8913,  c  = 21.387 Å), Sc 6 Co 2.18 In 0.82  (Ho 6 Co 2 Ga type,  Immm ,  a  = 8.867,  b  = 8.780,  c  = 9.321 Å), Sc 2 CoIn (Pt 2 ZnCd type,  P 4/ mmm ,  a  = 3.2887,  c  = 7.1642 Å), Sc 11 Co 4 In 9  (Nd 11 Pd 4 In 9  type,  Cmmm ,  a  = 13.836,  b  = 20.758,  c  = 3.351 Å), Sc 5 Co 2 In 4  (Lu 5 Ni 2 In 4  type,  Pbam ,  a  = 17.3400,  b  = 7.5940,  c  = 3.3128 Å), Sc 3 Co 1.64 In 4  (Lu 3 Co 2− x   In 4  type,  P6   ‾$\overline{6}$,  a  = 7.6702,  c  = 3.3595 Å), Sc 10 Co 9 In 20  (Ho 10 Ni 9 In 20  type,  P 4/ nmm ,  a  = 12.8331,  c  = 9.0226 Å), Sc 0.5 In 0.5 Co 2  (ternary non-centrosymmetric derivative of the Laves phase MgNi 2 ,  P 6 3   mc ,  a  = 4.8910,  c  = 16.0166 Å, with a homogeneity range from 12.3 to 16.7 at% of indium). The cubic phase ScCo 4 In (MgCu 4 Sn type,  F4   ‾$\overline{4}$3 m ,  a  = 6.9230(8) Å) is evidently present in the cast samples and disappears after the annealing procedure. A Sc/In substitution was observed for the solid solution Sc 1− x   In   x   Co 2  ( x  = 0–0.26) with the structure of the cubic Laves phase (MgCu 2  type) and also for the hexagonal Sc 0.5 In 0.5 Co 2 -type phase.

The ternary system Sc–Co–In at 870 K: the isothermal section and the crystal structures of the compounds