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A manganese(II) coordination polymer [Mn(tbip)(DMI)]   n    ( 1 ), (tbipH 2  = 5-( tert -butyl)isophthalic acid, DMI = 1,3-dimethyl-2-imidazolidinone), has been synthesized under “urea-thermal conditions” (i.e. in an excess of urea). Its structure has been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis and IR spectra. Complex  1  crystallizes in the monoclinic space group  P 2 1 / c  with  Z  = 4. In  1 , the [tbip] 2−  ligand bridges the Mn(II) cations to form infinite chains, and the neighbouring chains are connected through [tbip] 2−  ligands into layers.

Synthesis and structure of a manganese(II) coordination polymer assembled with 5-( tert -butyl)isophthalic acid and 1,3-dimethyl-2-imidazolidinone