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Two coordination polymers, [Zn 2 (bipmo) 2 (1,4-nda) 2 ]   n    ( 1 ), {[Cd(bipmo)(1,4-nda)]·(H 2 O)}   n    ( 2 ), (bipmo = bis(4-(1 H -imidazol-1-yl)phenyl)methanone, H 2 (1,4-nda) = naphthalene-1,4-dicarboxylic acid), were synthesized under solvothermal conditions. The complexes have been characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. Complex  1  possesses 3D 2-fold interpenetrating nets with the Schläfli symbol {6 5 ·8}. Complex  2  consists a 3D net with the Schläfli symbol {4 4 ·6 10 ·8}. The luminescent properties of complexes  1  and  2  have been investigated.

zeitschrift für naturforschung b

Two zinc and cadmium coordination polymers constructed with bis(4-(1 H -imidazol-1-yl)phenyl)methanone and naphthalene-1,4-dicarboxylate ligands: synthesis and structural characterization