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The one-pot reaction of dimethyl  N -cyanodithioiminocarbonate, [(MeS) 2 C=N–C≡N] with  n -butyltin trichloride, Sn( n -Bu)Cl 3  led to a dinuclear complex [Sn( n -Bu)Cl 2 (OH)(H 2 O)] 2  which co-crystallized with two [(MeS) 2 C=N–C≡N] molecules ( 1 ). The product was investigated by single-crystal X-ray diffraction analysis. Compound  1  crystallizes in the triclinic space groupP1   ‾$P\bar{1}$with  a  = 6.8048(6),  b  = 11.0645(9),  c  = 12.4240(10) Å,  α  = 66.3120(10),  β  = 75.6070(10),  γ  = 72.2940(10)°,  V  = 807.42(12) Å 3 ,  Z  = 1 and  Z ′ = 0.5. In the complex, two aqua- n -butyltin dichloride, [Sn( n -Bu)Cl 2 (H 2 O)] + , moieties are bridged by two hydroxide OH −  ions. Two inner O2–H2OB⋯Cl2 hydrogen bonds strengthen the dinuclear component which is connected to its neighbours through a O1–H1O⋯Cl1 hydrogen bond pattern giving rise to a network of infinite chains running parallel to the (100) direction. The dimethyl  N -cyanodithioiminocarbonate molecules are linked to these infinite chains through O2–H2OA⋯N1 hydrogen bonding interactions of D type. The [(MeS) 2 C=N–CN] molecules exhibits a minor positional disorder. These hydrogen bonding interactions lead to cyclic patterns generatingR   1   1(   6   )${\text{R}}_{1}^{1}\left(6\right)$andR   2   2(   8   )${\text{R}}_{2}^{2}\left(8\right)$rings. Weak C–H⋯Cl hydrogen bonds also contribute to the stability of the crystal structure.

Co-crystallization of dimethyl N -cyanodithioiminocarbonate and bis[(aqua)- µ 2 -hydroxy- n -butyldichlorotin(IV)]