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A new coordination polymer {[Cd(BIPA)(DCPS)](H 2 O)}   n    ( 1 ) was constructed with bis(4-(1H-imidazole-1-yl)phenyl)amine and 4,4′-sulfonyldibenzoate ligands. The complex  1  features (BIPA–Cd–BIPA)   n    and (DCPS–Cd–DCPS)   n    helical chains in a 3D architecture assembled via hydrogen bonds. A spectroscopic study of complex  1  in the crystalline state showed an intense red-shifted photoluminescence as compared with the ligands BIPA and DCPS 2− , which can be attributed to the ligand-to-metal charge transfer (LMCT) transitions.

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Synthesis and structural characterization of a luminescent cadmium(II) complex with bis(4-(1H-imidazole-1-yl)phenyl)amine and 4,4′-sulfonyldibenzoate ligands