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Reactions of lanthanide nitrate, 1,3,5-benzenetrisbnzoic acid (H 3 BTB) and [RMI]Br ionic liquids (RMI = 1-alkyl-3-methylimidazolium; R = ethyl, propyl or butyl), gave rise to six novel lanthanide–organic frameworks (LOFs) [Ln(BTB)H 2 O], where Ln = Nd  1 , Sm  2 , Gd  3 , Dy  4 , Ho  5  and Er  6 . These compounds have been characterized by elemental analysis, IR spectra, thermogravimetric analysis, single-crystal and powder X-ray diffraction. Compounds  1 – 6  are isostructural and consist of infinite rod-shaped lanthanide-carboxylate building units, which are further bridged by trigonal-planar BTB ligands to give non-interpenetrated open 3D frameworks. The results of variable-temperature magnetic studies have shown that the magnetic interaction between the Ln(III) ions in  3 ,  5  and  6  is mainly due to antiferromagnetic coupling as well as the depopulation of the Stark levels.

Syntheses directed by ionic liquids: structures and properties of six novel lanthanide 1,3,5-benzenetrisbenzoate frameworks