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A new cadmium(II)-based coordination polymer [Cd 3 (FcCOO) 6 (4,4′-bipy)(H 2 O) 2 ]   n    (FcCOO = ferrocenecarboxylato and 4,4′-bipy = 4,4′-bipyridine) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. The results of a crystal structural analysis has revealed that the title compound consists of two crystallographically unique Cd II  centers, one in a general position with a five-coordinated and one on an inversion center with a six-coordinated environment. The Cd II  centers are connected by FcCOO −  units to form a metal carboxylate oxygen chain extending parallel to the [100] direction while the 4,4′-bipy ligands further act as bridging linkers of the Cd II  centers resulting in a layered polymer. In addition, an X-ray powder diffraction and thermal gravimetric analysis and a cyclo-voltammetric characterization of the complex have also been carried out.

Synthesis, crystal structure and properties of a 2-D Cd(II) coordination polymer based on ferrocenecarboxylate and 4,4′-bipyridine ligands