English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The rare earth-rich indides Tm 4 IrIn and Lu 4 PtIn were synthesized by reaction of the elements in sealed tantalum ampules in an induction furnace. Tm 4 IrIn ( a  = 1340.77(4) pm) and Lu 4 PtIn ( a  = 1338.0(1) pm) crystallize with the Gd 4 RhIn-type structure, space groupF4   ‾3   m$F\overline{4}3m$. The Lu 4 PtIn structure was refined from single crystal X-ray diffractometer data:  wR  = 0.0524, 517  F  2  values and 20 variables. The striking crystal chemical motif is the  fcc  packing of In 4  tetrahedra with 318 pm In–In. The Lu 4 PtIn structure is closely related to the structures of Lu 13 Ni 6 In, Lu 14 Pd 3 In 3  and Lu 20 Ir 5 In 3  which all show icosahedral indium coordination and different condensation patterns that build up the indium substructure that consists of a dumbbell in Lu 14 Pd 3 In 3  and a triangle in Lu 20 Ir 5 In 3 . The results of magnetic susceptibility measurements indicate Curie-Weiss paramagnetism for Tm 4 IrIn (7.76(1) µ B  per thulium atom) without magnetic ordering down to 2.5 K. Lu 4 PtIn is Pauli-paramagnetic.

Tm 4 IrIn and Lu 4 PtIn – In 4 tetrahedra embedded in RE 22 polyhedra