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In this work, a novel metal-organic framework (MOF) based on 2,6-di(1 H -imidazol-1-yl)naphthalene (L) and biphenyl-3,4′,5-tricarboxylic acid (H 3 bptc), namely [Co(L)(Hbptc)(H 2 O)] ( 1 ), has been prepared.  1  has a distinct infinite chain structure, further linked together by winding interactions to give the three-dimensional (3D) network structure.  1  was characterized by X-ray crystallography, infrared spectra (IR) spectroscopy, elemental and thermal analysis. Photoluminescence studies revealed that  1  shows a strong emission at 361 nm upon excitation at 290 nm at room temperature. Moreover,  1  can efficiently detect Fe 3+  ions by luminescence quenching.

A new luminescent metal-organic framework with 2,6-di(1 H -imidazol-1-yl)naphthalene and biphenyl-3,4′,5-tricarboxylic acid