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In this work, a new type of zinc(II) coordination polymer {[Zn(HIDC)(BBM) 0.5 ]·H 2 O}  n   (Zn-CP) was synthesized using 4,5-imidazoledicarboxylic acid (H 3 IDC) and 2,2-(1,4-butanediyl)bis-1,3-benzimidazole (BBM) under hydrothermal conditions. Its structure has been characterized by infrared spectroscopy, elemental analysis and single crystal X-ray diffraction analysis. The Zn(II) ion is linked by the HIDC 2−  ligand to form a zigzag chain by chelating and bridging, and then linked by BBM to form a layered network structure. Adjacent layers are further connected by hydrogen bond interaction to form a 3-D supramolecular framework. The solid-state fluorescence performance of Zn-CP shows that compared with free H 3 IDC ligand, its fluorescence intensity is significantly enhanced.

zeitschrift für naturforschung b

A 2-D Zn(II) coordination polymer based on 4,5-imidazoledicarboxylate and bis(benzimidazole) ligands: synthesis, crystal structure and fluorescence properties