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A new 2-dimensional (2D) zinc(II) coordination polymer based on a flexible bis(imidazole) ligand, namely, [Zn 2 (BIBP)(BPDC) 2 ·DMF]  n   ( 1 ) BIBP is 1,4-bis(4-(imidazole-1-yl)benzyl)piperazine and H 2 BPDC is benzophenone-2,4′-dicarboxylic acid), has been synthesized and characterized through single-crystal X-ray diffraction, infrared (IR) spectroscopy, and elemental and thermal gravimetric analysis. Complex  1  exhibits a 2D framework oriented parallel to [0 2 1] based on [Zn(BPDC)]  n   chains. The fluorescence and catalytic properties of complex  1  for the photodegradation of methylene blue were investigated.

zeitschrift für naturforschung b

Crystal structure and physical properties of a new two-dimensional zinc coordination polymer based on 1,4-bis(4-(imidazole-1-yl)benzyl)piperazine and benzophenone-2,4′-dicarboxylate ligands