English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Four solvent complexes of beryllium iodide were prepared by dissolving BeI 2  in N,N-dimethyl formamide (DMF), pyridine (Pyr),  N -methyl pyrrolidone (NMP) and 2,6-dimethyl pyridine (2,6-lutidine, Lut). Their crystal structures were established from single crystal X-ray diffraction. For [Be(DMF) 4 ]I 2  a new modification is reported (monoclinic, space group  P 2 1 / c ,  a  = 12.491(2),  b  = 11.593(2),  c  = 15.310(3) Å,  β  = 94.7073(6)°). In [Be(Pyr) 4 ]I 2  (monoclinic, space group  C 2/ c ,  a  = 17.8799(13),  b  = 7.6174(5),  c  = 18.2611(14) Å,  β  = 113.508(4)°) and [Be(NMP) 4 ]I 2  (orthorhombic, space group  Pbca ,  a  = 13.941(5),  b  = 15.754(3),  c  = 24.634(7) Å) homoleptic tetrahedral complex cations are formed, while the sterically demanding solvent ligand Lut yields a neutral complex with covalently bound iodine ligands [BeI 2 (Lut) 2 ] (monoclinic, space group  P 2 1 / c ,  a  = 7.8492(9),  b  = 24.265(3),  c  = 27.037(3) Å,  β  = 97.076(3)°). Their electrochemical stability with respect to their application as beryllium electrolytes for deposition of beryllium from solution is discussed.

Synthesis and crystal structures of β -[Be(DMF) 4 ]I 2 , [Be(Pyr) 4 ]I 2 , [Be(NMP) 4 ]I 2 and [BeI 2 (Lut) 2 ]