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A Selected set of 2,4-diaryl-7-oxo-1,2,4-thiadiazino[5,6- h ]quinoline-8-carboxylic acids  6a–e  has been prepared  via  reaction of the parent 7-chloro-8-nitro-10-cyclopropyl-6-fluoroquinolone  4  with the appropriate  N ′-(aryl)benzothiohydrazide  5a–e  in presence of triethylamine. Structures of the new heterocyclics  6a–e  are supported by spectral data and confirmed by single-crystal X-ray crystallography for  6a .

Facile synthesis of model 2,4-diaryl-1,3,4-thiadiazino[5,6- h ]fluoroquinolones