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A self-assembly reaction of Cd(NO 3 ) 2  · 4H 2 O, 3-ferrocenyl-5-(2-pyridyl)-pyrazole (Hfcpp), [Ag(SePh)]  n  , and Et 3 N in a mixed acetone-water solvent resulted in the formation of a heterometallic complex [Cd 2 {Ag(SePh)} 2  ( μ  3 -OH 2 ) 2 ( μ  2 , η  3 -fcpp) 4 ] · 2C 3 H 6 O ( 1 ) with a phenylselenolate ligand. The two cadmium and two silver centers are linked by four [ μ  2 , η  3 -fcpp] −  ligands and two  μ  3 -OH 2  water molecules. Each Cd atom is in a slightly distorted octahedral coordination environment, while each Ag atom shows a distorted tetrahedral coordination geometry, which is composed of two pyrazolyl nitrogen atoms, one selenium atom, and one oxygen atom.

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A heterometallic Cd/Ag/Se complex incorporating 3-ferrocenyl-5-(2-pyridyl)pyrazolato (fcpp) ligands: synthesis and structure of [Cd 2 {Ag(SePh)} 2 (μ 3 -OH 2 ) 2 (μ 2 ,η 3 -fcpp) 4 ]·2C 3 H 6 O