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The salt [Rh(III)(phpy) 2 (dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at  λ  max  = 607 nm with φ ϕ  = 10 −3  and  τ  = 3.7 ns in CH 2 Cl 2 .

Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy) 2 (dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl)