English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The rare earth metal-rich  RE  14  T  3 Al 3  series ( RE =Y, Gd–Tm, Lu;  T =Co, Ni) have been prepared by arc-melting the rare earth metals with appropriate amounts of  T Al precursors. All compounds crystallize in the tetragonal crystal system with space group  P 4 2 / nmc  in the Gd 14 Co 3 In 2.7 -type structure. Two structures (Y 14 Co 2.78(1) Al 3.22(1) :  a =952.99(4),  c =2292.98(10) pm,  wR 2=0.0423, 2225  F  2  values, 63 variables; Y 14 Ni 3.07(2) Al 2.93(2) :  a =955.06(5),  c =2298.77(10) pm,  wR 2=0.0416, 2225  F  2  values, 63 variables) have been refined from single-crystal data, indicating  T /Al mixing on one crystallographic site. The lattice parameters of all members have been refined from powder X-ray diffraction experiments. The Y and Lu containing compounds for  T =Co and Ni exhibit Pauli paramagnetic behavior, indicating that the Co and Ni atoms exhibit no localized magnetic moment in line with a filled 3 d  band. The other compounds show paramagnetism, in line with the rare earth atoms in the trivalent oxidation state. Detailed magnetic investigations, however, were impossible due to the presence of e.g.  RE  3  T  trace impurities.

zeitschrift für naturforschung b

Crystal structure and magnetic properties of the ternary rare earth metal-rich transition metallides  RE  14  T  3 Al 3  ( RE  = Y, Gd–Tm, Lu;  T  = Co, Ni)