English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The first ammonium indium borate (NH 4 )InB 8 O 14  was synthesized from indium oxide and boric acid under high-pressure/high-temperature conditions of 9 GPa and 1000°C with a Walker-type multianvil apparatus in a BN crucible. Although a reproduction of this synthesis product failed until now, we were able to determine the crystal structure  via  single-crystal X-ray diffraction data collected at room temperature. (NH 4 )InB 8 O 14  crystallizes in the monoclinic space group  P 2/ m  ( Z =2) with  a =4.4053(2),  b =7.8184(3),  c =12.4685(4) Å,  β =94.60(1)°, and  V =428.06(3) Å 3 . The structure comprises all three basic structural units of borates, namely corner-sharing BO 4  tetrahedra, edge-sharing BO 4  tetrahedra, and planar BO 3  groups. Large cavities in the borate network give space to disordered, isolated ammonium ions. The presence of nitrogen (confirmed by EDX analysis) appears to originate from the container material.

(NH 4 )InB 8 O 14 – a high-pressure borate combining BO 3 groups with corner- and edge-sharing BO 4 tetrahedra