English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Tools annual

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Presents the access of premium content as premium feature

Premium Content

Global: Zendy Plus annual

Global: Zendy Free Plan

The first mixed germanato-antimonato derivative of the {V 14 E 8 O 42 } (E=semi-metal) cluster archetype has been synthesized under hydrothermal conditions and isolated as {Ni(phen) 3 } 2 [α-V IV  14 Sb III  5 Ge IV  3 O 42 (OH) 3 (H 2 O)]· ≈16H 2 O (phen=1,10-phenanthroline). In the cluster anion, seven of the eight hetero-metal positions are occupied by disordered Ge/Sb atoms, while one position is fully occupied by Sb atoms. The [V 14 Sb 5 Ge 3 O 42 (OH) 3 (H 2 O)] 6−  anions are arranged in pairs with remarkably short inter-cluster Sb···O contacts. Bond valence sum calculation strongly suggests that the Sb···O contact must be taken into account as a weak bond. The magnetic properties are dominated by strong intra-cluster antiferromagnetic exchange interactions, and the cluster anion is magnetically quasi-isolated from the spins of the Ni 2+  complex cations.

Mixing Sb III and Ge IV occupancy in the polyoxovanadate {V 14 E 8 } archetype