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Silver cyanide can be treated with liquid amines or azaaromatics  L  to give crystalline complexes of various compositions, among them complexes of the simple type cyanido(amine)silver(I):  L =isobutylamine and 4-picoline. Other AgCN: L  ratios obtained were: 1:2 (benzylamine and 4-benzylpiperidine), 2:1 (2,4-lutidine), 2:3 (morpholine and 3,4-lutidine) and 3:4 (3,5-lutidine). The packing diagrams were analyzed in terms of Ag–Ag and Ag–CN contacts and N–H ··· N hydrogen bonds. The contacts often give rise to chains, which are sometimes linked to layers by hydrogen bonds.

Silber(I)-cyanid-Komplexe mit Aminen und Azaaromaten