English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

A new silver(I) complex with 1,3-bis(1-benzylbenzimidazol-2-yl)-2-thiapropane (bbbt) and crotonate ligands, with composition [Ag(bbbt)(crotonate)]·CH 3 CH 2 OH, has been synthesized and characterized by physicochemical and spectroscopic methods. Single-crystal X-ray diffraction revealed that the coordination environment of the silver(I) center can be described as a distorted tetrahedral geometry, the Ag(I) atom being coordinated by two oxygen atoms from a crotonate anion and two nitrogen atoms from a bbbt ligand. Experimental studies of the DNA-binding properties indicated that the free ligand and the silver(I) complex bind to DNA by intercalation, and the order of the binding affinity is silver(I) complex&gt;free bbbt ligand. The Ag(I) complex exhibits scavenger properties for hydroxyl radicals in  in vitro  studies.

zeitschrift für naturforschung b

Synthesis, crystal structure and biological activities of a Ag(I) complex based on the V-shaped ligand 1,3-bis(1-benzylbenzimidazol-2-yl)-2-thiapropane