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Two complexes, {Mn(hfac) 2 (BIPMO)}  n   ( 1 ), {Cu(hfac) 2 (BIPMO)}  n   ( 2 ) [hfac=1,1,1,5,5,5-hexafluoro-pentane-2,4-dionato(–), BIPMO=bis(4-(1 H -imidazol-1-yl)phenyl)methanone], with the V-shaped ligands were synthesized and characterized by infrared spectroscopy, elemental analyses, along with single-crystal X-ray diffraction analyses. The X-ray diffraction studies have shown that the metal ions in  1  and  2  are both six-coordinated to two nitrogen atoms of two BIPMO ligands and four oxygen atoms of two hfac ligands to form a distorted octahedral geometry. Each BIPMO ligand acts as a bridging ligand to link two adjacent metal(II) atoms to form a helical chain in the crystal structure.

Synthesis and structural characterization of Mn(II) and Cu(II) complexes with bis(4-(1 H -imidazol-1-yl)phenyl)methanone ligands