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Well-shaped needles of the metal-rich phosphide Ce 2 Ru 12 P 7  were grown in a lead flux, while a polycrystalline sample became available through a ceramic route followed by arc-melting. Ce 2 Ru 12 P 7  crystallizes with the hexagonal Zr 2 Fe 12 P 7  type:  P 6̅,  a  = 940.7(2),  c  = 389.8(1) pm,  wR 2 = 0.0342, 1001  F  2  values and 45 variables. Striking structural motifs in the Ce 2 Ru 12 P 7  structure are tri-capped trigonal prisms that are centered by the phosphorus atoms: P1@Ru 7 Ce 2 , P2@Ru 7 Ce 2  and P3@Ru 9 . Adjacent prisms are condensed via common edges to propeller-like building units.

Lead flux crystal growth of Ce 2 Ru 12 P 7