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Two new complexes, [Ni(pydc)(H 2 O) 3 ] ( 1 ) and [Ni(cma)(H 2 O) 3 ] ( 2 ) (H 2 pydc = pyridine-2,6-dicarboxylic acid, H 2 cma = 2-(carboxymethoxy)benzoic acid), have been synthesized and structurally characterized. In both compounds, Ni II  is surrounded by one tridentate chelate dianionic ligand (pydc 2 ˉ for  1  and cma 2 ˉ for  2 ) and three coordinated water molecules in a distorted octahedral geometry (NiNO 5  for  1  and NiO 6  for  2 ). The magnetic properties for  1  and  2  have been discussed in detail.

Syntheses, structures and magnetic properties of two mononuclear nickel(II) complexes based on bicarboxylate ligands