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Three new cesium oxometallates with trigonal-planar [MO 3 ] n−  anions (M = Zn, Fe, B) were observed as products of reactions aimed at the formation of alkali metal suboxometallates A9MO4 (A = Rb, Cs; M = Al, Ga, In, Fe, Sc), or as decomposition products thereof. Cs 4 [FeO 3 ], Cs 4 [ZnO 3 ] and Cs 3 [BO 3 ] crystallize with new structure types (Cs 4 [FeO 3 ]: triclinic, space group P1̄

zeitschrift für naturforschung b

The New Oxometallates Cs 4 [FeO 3 ], Cs 4 [ZnO 3 ] and Cs 3 [BO 3 ] with Trigonal-planar Anions – Decomposition Products of Alkali Metal Suboxometallates