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Two new complex copper(II) sulfates [Cu(1,10-phen)(H 2 O) 2 ]SO 4  (1, 1,10-phen = 1,10-phenanthroline) and [Cu(2,2′-bipy)(H 2 O) 2 ]SO 4  (2, 2,2′-bipy = 2,2′-bipyridine) have been hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, and X-ray crystallography. 1 and 2 consist of complex cations [Cu(1,10-phen/2,2′-bipy)(H 2 O) 2 ] 2 + and SO 4  2−  anions, which are interconnected via weak Cu・ ・ ・O interactions to form rare examples of 1-D metal sulfates

Hydrothermal Synthesis and Structure of Two 1-D Organic HybridMetal Sulfates