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Two novel cadmium coordination polymers, [Cd(pydc)2(tu)]n (1) and [Cd 2 (SO 4 )(nic) 2 (tu) 1.5  - (H 2 O) 2 ] n  (2) (pydc = pyridine-2,3-dicarboxylate, nic = nicotinate, tu = thiourea), have been synthesized under hydrothermal conditions and structurally characterized by X-ray diffraction analysis. 1 is a one-dimensional ladder coordination polymer in a two-dimensional network formed by hydrogen bonds. 2 consists of two kinds of Cd(II) centers in different coordination environments connected via nicotinate and sulfate to form a two-dimensional grid network integrated in a three-dimensional framework generated by hydrogen bonds. 2 shows intense fluorescent emission in the solid state at room temperature

zeitschrift für naturforschung b

Syntheses, Structures and Photoluminescent Properties of the Two Novel Coordination Polymers [Cd(pydc) 2 (tu)] n  and [Cd 2 (SO 4 )(nic) 2 (tu) 1.5 (H 2 O) 2 ]n (pydc = Pyridine-2,3-dicarboxylate, nic = Nicotinate, tu = Thiourea)