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Single crystals of Cs 2 (UO 2 )(NO 3 )Cl 3  were prepared by a hydrothermal method at 205 °C. The crystal structure has been solved by Direct Methods: monoclinic, P2 1 /n, a = 10.3748(13), b = 9.4683(13), c = 12.5535(16) Å, β = 110.280(2)◦, V = 1156.7(3) Å 3 , R 1  = 0.029. In the structure, strongly bonded linear uranyl cations UO 2  2+  are equatorially coordinated by two O and three Cl atoms to form (UO 2 )Cl 3 O 2  pentagonal bipyramids. Each bipyramid shares its O-O edge with an adjacent (NO 3 ) −  anion to form finite clusters with the chemical composition [(UO 2 )(NO 3 )Cl 3 ] 2− . The Cs+ cations provide three-dimensional connectivity of the structure by forming Cs-O and Cs-Cl contacts to the uranyl nitrate chloride complexes. Related structures of mixed-ligand uranyl halides are compared.

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Crystal Chemistry of Uranyl Halides Containing Mixed (UO 2 )(X m O n ) 5  Bipyramids (X = Cl, Br): Synthesis and Crystal Structure of Cs 2 (UO 2 )(NO 3 )Cl 3