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A new centrosymmetric trinuclear Zn(II) complex [Zn 3 L 2 (CH 3 COO) 4 ] (1) has been synthesized by the reaction of Zn(CH 3 COO) 2  · 2H 2 O with a tridentate N,N,O-donor Schiff base ligand HL [C 5 H 4 NC(CH 3 )=NC 6 H 4 (OH)] and systematically characterized by elemental analysis, FT-IR, UV/Vis and thermal methods. Single crystal X-ray structure analysis reveals that three Zn(II) centers are in two different coordination environments. Two terminal Zn(II) centers adopt a distorted squarepyramidal geometry leaving the central Zn(II) in a distorted octahedral environment. Two adjacent metal centers are connected through single μ 2 -phenolato as well as double μ-acetato-O,O´ syn-syn bridges. Fluorescence properties of the complex as compared to the ligand indicate that the former can serve as a potential photoactive material.

Synthesis, Structure and Fluorescence Properties of a Trinuclear Zn(II) Complex with N,N,O-donor Schiff Base Ligands and Bridging Acetates