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New intermetallic compounds Sc 50 Rh 13.3 In 2.7  and Sc 50 Ir 13.6 In 2.4  and the suboxides Sc 49.2 Rh 13 In 3.8 O 8.8  and Sc 49.2 Rh 13.7 In 2.8 O 8.0  were synthesized from the elements or with Sc 2 O 3  as an oxygen source, respectively, in sealed tantalum tubes in a water-cooled sample chamber of an induction furnace. They crystallize with a new cubic structure type, space group Fm3̅, a = 1772.5(6) pm, wR2 = 0.032, 1111 F 2  values, 34 variables for Sc 50 Rh 13.3 In 2.7 , a = 1766.5(6) pm, wR2 = 0.041, 745 F 2  values, 34 variables for Sc 50 Ir 13.6 In 2.4 , a = 1764.4(2) pm, wR2 = 0.044, 690 F2 values, 41 variables for Sc 49.2 Rh 13 In 3.8 O 8.8 , and a = 1761.5(6) pm, wR2 = 0.054, 740 F2 values, 42 variables for Sc 49.2 Rh 13.7 In 2.8 O 8.0 . The main structural motifs are rhodium-centered indium cubes in an fcc like arrangement in which the octahedral and tetrahedral voids are filled by In 2 Sc 12  and In 1 Sc 12  icosahedra, respectively, resembling a Li3Bi-like structure. The Rh1 (Ir1) and Sc4 atoms lie between these polyhedral units. The oxygen atoms partially fill Sc 6  octahedra in Sc 49.2 Rh 13 In 3.8 O 8.8  and Sc 49.2 Rh 13.7 In 2.8 O 8.0  with Sc-O distances of 214 - 230 pm. These octahedra are condensed via common edges and faces, encapsulating the In 2 Sc 12  icosahedra. Due to the high scandium content one observes strong Sc-Sc bonding with Sc-Sc distances ranging from 303 to 362 pm in Sc 49.2 Rh 13 In 3.8 O 8.8 . The shortest distances occur for Sc-Rh (267 - 295 pm). The crystal chemical relationship with the Li 3 Bi-related suboxide Ti 12 Sn 3 O 10  is discussed.

Ternary Scandium-rich Indides Sc 50 T 13 In 3 and Sc 50 Rh 13 In 3 O y (T = Rh, Ir; y ≈ 8) – Synthesis and Crystal Structure