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The applicability of the tin(II) polyoxometalate catalyst, [(n-C 4 H 9 ) 4 N] 5 PSnMo 2 W 9 O 39  · 9H 2 O, for sulfoxidation of diaryl, dibenzyl, aryl benzyl, dialkyl, cyclic, and heterocyclic sulfides with 30% hydrogen peroxide was examined under organic halogen-free condition. It is noteworthy that different functional groups including carbon-carbon double bonds, ketones, oximes, aldehydes, ethers, alcohols, and acetals were tolerated under this reaction condition.

Tin(II) Polyoxometalate as an Efficient Catalyst for the Selective Oxidation of Sulfides to Sulfoxides