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The reaction of Fc(S 2 CNEt 2 ) 2  (Fc = Fe(η 5 -C 5 H 4 ) 2 ) with [Ag(OTf)(PPh 3 )] (OTf = trifluoromethanesulfonate) or [Au(OClO 3 )(PPh 3 )] in various molar ratios gives complexes of stoichiometry [Ag(PPh 3 ){Fc(S 2 CNEt 2 ) 2 }]OTf, [Ag(PPh 3 ) 2 {Fc(S 2 CNEt 2 ) 2 }]OTf, [Ag 2 (PPh 3 ) 2 {Fc(S 2  CNEt 2 ) 2 }](ClO 4 ) 2 or [Ag 3 (PPh 3 ) 3 {Fc(S 2 CNEt 2 ) 2 }](ClO 4 ) 3 . Treatment of Fc(S 2 CNEt 2 ) 2  with Ag(OTf) gives the complex [Ag(OTf){Fc(S 2 CNEt 2 ) 2 }], which can easily react with bidentate ligands such as 1,10-phenanthroline (phen), bis(diphenylthiophosphoryl)methane ((SPPh 2 ) 2 CH 2 ) or NaS 2 CNEt 2  to afford the cationic complexes [Ag(phen){Fc(S 2 CNEt 2 )-}]OTf, [Ag{(SPPh 2 ) 2  CH 2 }{Fc(S 2 CNEt 2 ) 2 }]OTf or the neutral [Ag(S 2 CNEt 2 ){Fc(S 2 CNEt 2 ) 2 }]. The crystal structure of [Ag(PPh 3 ) 2 {Fc(S 2 CNEt 2 ) 2 }]OTf reveals that silver coordinates to the dithiocarbamate sulfur atoms of two ferrocene ligands, thus forming a chain polymer.

Silver(I) Complexes with the 1,1’-Bis(diethyldithiocarbamate)ferrocene Ligand. Polymeric Chain Species