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The new copper(I) coordination polymer poly[tri-μ 2 -cyano-C,N)-bis(μ 2 -2,3-dimethyl-pyrazine- N,N)] tricopper(I) ( I ) was prepared by the reaction of copper(I) cyanide with 2,3-dimethylpyrazine in acetonitrile. In the crystal structure of  I a novel CuCN substructure is found which is connected by the dimethylpyrazine ligands into a three-dimensional coordination network. The thermal properties of  I were investigated using simultaneous differential thermoanalysis (DTA), thermogravimetry (TG) and mass spectrometry (MS) as well as temperature resolved X-ray powder diffraction. On heating, compound  I looses a part of the dimethylpyrazine ligands in an endothermic reaction to form the known ligand poor compound (CuCN) 2 -(2,3-dimethylpyrazine)  II as an intermediate which decomposes to CuCN on further heating.

zeitschrift für naturforschung b

Synthesis, Crystal Structure and Thermal Decomposition Reaction of the New Copper(I) Cyanide Coordination Polymer Poly[tri-μ 2 -cyano-C,N)- bis(μ 2 -2,3-dimethyl-pyrazine-N,N)]tricopper(I)