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The metalation of tri(tert-butyl)silylphosphane with diethylzinc yields quantitatively the title compound tetraethyltetrakis(tri(tert-butyl)silylphosphanediido)hexazinc (1) with a novel Zn 6 P 4  cage with two Zn 2 P 2  rings interconnected by two zinc atoms.

(EtZn) 4 Zn 2 (PSitBu 3 ) 4 – a Homometallic Phosphanediide of Zinc with a Novel Zn 6 P 4 Cage