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The cation Al 2 Cp* +  descending from the tetrahedral Al 4 Cp* 4  Cluster after using LDI as ionisation method in an FT-ICR mass spectrometer reacts with Cl 2  in the gas phase. The investigation of this reaction together with quantum chemical calculations gives a new approach to the question of existence and stability of an aluminum-aluminum double bond.

zeitschrift für naturforschung b

Strukur und Reaktivität von Al 2 Cp* +  in der Gasphase. Ein experimenteller Beitrag zur Problematik der Aluminium-Aluminium- Doppelbindung / Structure and Reactivity of Al 2 Cp* +  in the Gas Phase. Experiments on the Problematic Nature of the Aluminum-Aluminum-Multiple Bond