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Heteropolynuclear gold(I)-thallium(I) complexes of the type [TlL n ][Au(C 6 F 5 ) 2 ] (L = py (2), 2,2’- bipy (3), 1,10-phen (4) or 4,4’-bipy and THF (5); n = 1, 2) have been obtained from reactions of the corresponding N-donor ligands with the precursor {Tl[Au(C 6 F 5 ) 2 ]} n  (1). The crystal structures of complexes 3 - 5 have been determined by X-ray diffraction showing one- (3, 4) or three-dimensional (5) arrays. All complexes are photoluminescent in the solid state at RT and at 77 K. The strong visible emissions of complexes 2 - 5 are displayed over a wide range of wavelengths (460 - 620 nm) depending on the environment of the thallium(I) centres and on the nature of the N-donor ligand.

Luminescent Gold(I)-Thallium(I) Arrays through N-Bidentate Building Blocks