English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The reaction of diastereomeric methyl rhenium complexes [CpRe(NO)(NMDPP)(CH 3 )] (NMDPP = neomenthyl-diphenylphosphine) and [CpRe(NO)(PAMP)(CH 3 )] (PAMP = phenyl-2- anisyl-methylphosphine) with thiols in the presence of HBF 4  gave thiolate complexes [CpRe(NO)(NMDPP)(SCH 2 Ph)] and [CpRe(NO)(PAMP)(SCH 2 R)] (R = Ph, 4-C 6 H 4 Cl, 4-C 6 H 4 OMe, 2-C 4 H 3 O, CH 3 , CH=CH 2 ). Treatment of [CpRe(NO)(PAMP)(THF)]BF 4  with the thiols and Na 2 CO 3  gave the same compounds under neutral conditions. Similarly, the reaction of the chelate complex {CpRe(NO)[κP(Ph)(Me)(CH 2 C 4 H 3 κS)]}BF 4  with thiols and NaOEt yielded the ring-opened products {CpRe(NO)[P(Ph)(Me)(CH 2 C 4 H 3 S)](SCH 2 R)} (R = Ph, 4-C 6 H 4 Cl, 4-C 6 H 4 OMe). One of the benzylic hydrogen atoms can be abstracted with [Ph 3 C]BF 4  to give the diastereomeric thiobenzaldehyde complexes [CpRe(NO)(PAMP)(S=CHR)]BF 4  (R = Ph, 4-C 6 H 4 Cl, 4-C 6 H 4 OMe) and {CpRe(NO)[P(Ph)(Me)(CH 2 C 4 H 3 S)](S=CHPh)}BF 4 . In these products, the thioformyl group is predominantly η 2 (C,S) coordinated to rhenium, but in a few cases the corresponding η 1 (S) isomers were also detected by IR and NMR spectroscopy.

Diastereomeric Halfsandwich Rhenium Complexes Containing Thiolate and Thioaldehyde Ligands