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The organoindium subhalide [R(Cl)In-In(Cl)R] 2  [R = C(SiMe 3 ) 3 ] 1 reacts with Na 2 [Fe 2 (CO) 8 ] to form an iron-indium coordination compound which was isolated as the sodium choride adduct [Na(THF) 4 ][Fe 2 (CO) 6 (μ-CO)(μ-InR) 2 Cl] 2. The iron atoms of 2 are bridged by a CO ligand and two InR groups, the indium atoms of which are further connected by the μ 2 -bridging chlorine atom. Four THF molecules and two oxygen atoms of terminal CO ligands of different anions span the coordination sphere of the sodium cations to give a one-dimensional coordination polymer in the solid state.

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The NaCl Adduct of the Iron-Indium Compound Fe 2 (CO) 6 (μ-CO)(μ-InR) 2  [R = C(SiMe 3 ) 3 ] – a One-Dimensional Coordination Polymer with Sodium Oxygen Bridges