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The 1,1-dithiolates Ph 2 C═N-C(CO 2 Et)═CS 2  2−  and Me 2 NC(CO 2 Et)═CS 2  2−  from diphenylmethylene glycine ethylester or N,N-dimethylglycine ester and CS 2  react under basic conditions with chlorophosphine compounds of Pd(II), Pt(II) and gold(I) to give the complexes Ph 2 C═N-C(CO 2 Et)═CS 2 ML 2 , Me 2 N-C(CO 2 Et)═CS 2 ML 2  (M = Pd, Pt; L = PPh 3 , 2L = Ph 2 PCH 2 CH 2 PPh 2 ) and Ph 2 C═N-C(CO 2 Et)═CS 2 (AuPPh 3 ) 2 , and Me 2 N- C(CO 2 Et)═CS 2 (AuPPh 3 ) 2 .

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Metallkomplexe mit biologisch wichtigen Liganden, CL [1]. 1,1-Dithiolato-Komplex von Palladium(II), Platin(II) und Gold(I) aus Diphenylmethylenglycinester sowie N,N-Dimethylglycinester und Schwefelkohlenstoff