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Reaction of freshly precipitated Mn(OH) 2−2x (CO 3 ) x  · yH 2 O, adipic acid and phenanthroline in CH 3 OH/H 2 O afforded a new dinuclear Mn(II) complex, Mn 2 (phen) 2 (H 2 O) 2 (C 6 H 8 O 4 ) 2  1, aside the known [Mn(phen) 2 (H 2 O)(C 6 H 8 O 4 )]·7H 2 O 2. Single crystal X-ray analyses showed that complex 1 consists of the centrosymmetric dinuclear molecules resulting from two [Mn(phen)(H 2 O)] 2+  moities bridged by two twisted tridentate adipato ligands. The Mn atoms are each in severely distorted octahedral geometry defined by two N atoms of one phen ligand, three carboxyl O atoms of two adipato ligands and one H 2 O molecule with d(Mn-N) = 2.246 and 2.296 Å and d(Mn-O) = 2.066 - 2.339 Å . The complex molecules are assembled via π-π stacking interactions into 2D layers, which are held together by both strong O-H ··· O and weak C- H ··· O hydrogen bonds. The thermal behavior of 1 and 2 upon heating in argon stream is discussed.

New Dinuclear Mn(II) Phenanthroline Adipato Complex: Synthesis and Structural and Thermal Characterization of Mn 2 (phen) 2 (H 2 O) 2 (C 6 H 8 O 4 ) 2